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cyclophane

n. 1 (context organic chemistry English) A hydrocarbon consisting an aromatic unit (typically a benzene ring) and an aliphatic chain that forms a bridge between two positions of the aromatic ring; more complex derivatives (the superphanes) with multiple aromatic units and bridges forming cagelike structures are known. 2 (context organic chemistry English) Any cyclic structure used as a base phane in the nomenclature of complex organic compounds

Wikipedia
Cyclophane

A cyclophane is a hydrocarbon consisting of an aromatic unit (typically a benzene ring) and an aliphatic chain that forms a bridge between two non-adjacent positions of the aromatic ring. More complex derivatives with multiple aromatic units and bridges forming cagelike structures are also known. Cyclophanes are well-studied in organic chemistry because they adopt unusual chemical conformations due to build-up of strain. Despite this, cyclophane structures are not unknown to biomolecules.

Basic cyclophane types are [n]metacyclophanes (I) in scheme 1, [n]paracyclophanes (II) and [n,n']cyclophanes (III). the prefixes meta and para correspond to the usual arene substitution patterns and n refers to the number of atoms making up the bridge.