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hyperconjugation

n. (label en organic chemistry) A weak form of conjugation in which single bonds interact with a conjugated system

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Hyperconjugation

In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non-bonding p-orbital, antibonding σ or π orbital, or filled π orbital, to give an extended molecular orbital that increases the stability of the system. Only electrons in bonds that are β to the positively charged carbon can stabilize a carbocation by hyperconjugation.