Wiktionary
a. (context chemistry English) not able to be saponified; used of those lipids (such as steroids) that are not glycerides
Wikipedia
Unsaponifiables are components of an oily ( oil, fat, wax) mixture that fail to form soaps when blended with sodium hydroxide ( lye) or potassium hydroxide. Since saponifiable components of the original oil mixture do form soaps, the result of a soap making procedure is a mixture of soaps and other, frequently oily, materials.
Unsaponifiable constituents are an important consideration when selecting oil mixtures for the manufacture of soaps. Unsaponifiables can be beneficial to a soap formula because they may have properties such as moisturization, conditioning, vitamins, texture, etc. On the other hand, if the proportion of unsaponifiables is too high, or the specific unsaponifiables present do not provide significant benefits, a defective or inferior soap product can result.
Usage examples of "unsaponifiable".
The unsaponifiable matter in these is purely natural, it will be seen it varies within wide limits.