Wikipedia
Patio process
The patio process was a process used to extract silver from ore. The process was invented by Bartolomé de Medina in Pachuca, Mexico, in 1554. The patio process was the first process to use mercury amalgamation to recover silver from ore. It replaced smelting as the primary method of extracting silver from ore at Spanish colonies in the Americas. Other amalgamation processes were later developed, importantly the pan amalgamation process, and its variant, the Washoe process. The silver separation process generally differed from gold parting and gold extraction, although amalgamation with mercury was also sometimes used to extract gold.