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myrosinase

n. (context enzyme English) Any of several defense-related enzymes, in plants such as mustard, that hydrolyze glycosides thus releasing potentially toxic substances

Wikipedia
Myrosinase

Myrosinase (, thioglucoside glucohydrolase, sinigrinase, and sinigrase) is a family of enzymes involved in plant defense against herbivores. The three-dimensional structure has been elucidated and is available in the PDB (see links in the infobox).

A member of the glycoside hydrolase family, myrosinase possesses several similarities with the more ubiquitous O- glycosidases. However, myrosinase is the only known enzyme found in nature that can cleave a thio-linked glucose. Its known biological function is to catalyze the hydrolysis of a class of compounds called glucosinolates.