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Douglas Harper's Etymology Dictionary
liveware

"people," 1966, computer-programmer jargon, from live (adj.) + ending abstracted from software, etc.\n

Wiktionary
liveware

n. (context colloquial English) people who work with computers, as opposed to the software or hardware they use; ''loosely'', human beings, as opposed to technology. (from 20th c.)

Wikipedia
Liveware

Liveware was used in the computer industry as early as 1966 to refer to computer users, often in humorous contexts, by analogy with hardware and software.

It is a slang term used to denote people using (attached to) computers, and is based on the need for a human, or liveware, to operate the system using hardware and software. Other words meaning the same or similar to liveware include wetware, meatware and jellyware. Meatware and jellyware are most often used by internal customer support personnel as slang terms when referencing human operating errors. The term liveware is found in the Culture novels by Iain M. Banks. A Culture Ship is named "Liveware Problem". This is likely a pun on a common computing jargon hinting at the fact that the problem lies with the system's user.

Usage examples of "liveware".

We're keeping the contracts going with liveware right now, but we can't afford their salaries much longer.