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Bis(trimethylsilyl)acetylene

Bis(trimethylsilyl)acetylene (BTMSA) is an organosilicon compound with the formula C(Si(CH)). It is a colorless liquid that is soluble in organic solvents. This compound is used as a surrogate for acetylene.

BTMSA is prepared by treating acetylene with butyl lithium followed by addition of chlorotrimethylsilane:

LiC + 2 (CH)SiCl → [(CH)Si]C + 2 LiCl