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Answer for the clue "Villain played by Josh Brolin in most "Avengers" films ", 6 letters:
thanos

Word definitions for thanos in dictionaries

Wikipedia Word definitions in Wikipedia
Thanos (, ) is a fictional supervillain appearing in American comic books published by Marvel Comics . The character is usually depicted as a Titanian mutant - eternal superhuman. The character first appeared in Iron Man #55 (Feb. 1973) and was created ...