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Answer for the clue "Rio de Janeiro is its capital ", 9 letters:
guanabara

Word definitions for guanabara in dictionaries

Wikipedia Word definitions in Wikipedia
The State of Guanabara (, ) was a Brazilian city - state that existed from 1960 to 1975. It comprised only the city of Rio de Janeiro after the Federal District was moved from that city to Brasília in 1960. The state was named after Guanabara Bay , along ...