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Answer for the clue "Process of treating rubber or rubberlike materials with sulphur at great heat to improve elasticity and strength or to harden them ", 13 letters:
vulcanisation

Word definitions for vulcanisation in dictionaries

WordNet Word definitions in WordNet
n. process of treating rubber or rubberlike materials with sulphur at great heat to improve elasticity and strength or to harden them [syn: vulcanization ]

Wiktionary Word definitions in Wiktionary
n. (standard spelling of from=Non-Oxford British spelling lang=en vulcanization)