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Answer for the clue "Large and economically important family of herbs or shrubs or trees often strongly scented and sometimes narcotic or poisonous ", 10 letters:
solanaceae

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Wikipedia Word definitions in Wikipedia
The Solanaceae , or nightshades , are an economically important family of flowering plants . The family ranges from annual and perennial herbs to vines, lianas, epiphytes, shrubs, and trees, and includes a number of important agricultural crops, medicinal ...