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Answer for the clue "The swelling of certain substances when they are heated (often accompanied by release of water) ", 12 letters:
intumescency

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Word definitions for intumescency in dictionaries

WordNet Word definitions in WordNet
n. swelling up with blood or other fluids (as with congestion) [syn: intumescence ] the swelling of certain substances when they are heated (often accompanied by release of water) [syn: intumescence , swelling ]