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Answer for the clue "Adsorption (especially when irreversible) by means of chemical instead of physical forces ", 13 letters:
chemosorption

Word definitions for chemosorption in dictionaries

WordNet Word definitions in WordNet
n. adsorption (especially when irreversible) by means of chemical instead of physical forces; "chemisorption of gaseous nitrogen on iron catalysts" [syn: chemisorption ]

The Collaborative International Dictionary Word definitions in The Collaborative International Dictionary
chemosorption \chemosorption\ n. adsorption (especially when irreversible) by means of chemical instead of physical forces; as, chemosorption of gaseous nitrogen on iron catalysts. Syn: chemisorption.