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Tolidine

2-Tolidine (orthotolidine, o-tolidine) is an organic compound with the chemical formula (CH(CH)NH). Several isomers are known; the 3-tolidine derivative is also important commercially. It is a colorless compound although commercial samples are often colored. It is slightly soluble in water. It forms salts with acids, such as the hydrochloride, which is commercially available.

2-Tolidine can be produced by a benzidine rearrangement from a hydrazine derivative derived from 2-nitrotoluene.

(CHCH)NH → (CH(CH)NH)