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Thiosulfinate

In organosulfur chemistry, thiosulfinate is a functional group consisting of the linkage R-S(O)-S-R (R are organic substituents). Thiolsulfinates are also named as alkanethiosulfinic (or arenethiosulfinic) acid esters. They are the first member of a family of compounds containing an oxidized disulfide bond. Other members of this family include thiosulfonates, R-SO-S-R, α-disulfoxides, R-S(O)-S(O)-R, sulfinyl sulfones, R-S(O)-SO-R, and α-disulfones, R-SO-SO-R, all of which are known. The thiosulfinate group can occur in cyclic as well as acyclic structures.