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Sodium oxide

Sodium oxide (SOX) is a chemical compound with the formula Na O. It is used in ceramics and glasses, though not in a raw form. It is the base anhydride of sodium hydroxide, so when water is added to sodium oxide NaOH is produced.

NaO + HO → 2 NaOH

The alkali metal oxides MO (M = Li, Na, K, Rb) crystallise in the antifluorite structure. In this motif the positions of the anions and cations are reversed relative to their positions in CaF, with sodium ions tetrahedrally coordinated to 4 oxide ions and oxide cubically coordinated to 8 sodium ions.