Wikipedia
The Playfair cipher or Playfair square or Wheatstone-Playfair cipher or Wheatstone cipher is a manual symmetric encryption technique and was the first literal digram substitution cipher. The scheme was invented in 1854 by Charles Wheatstone, but bears the name of Lord Playfair who promoted the use of the cipher.
The technique encrypts pairs of letters ( bigrams or digrams), instead of single letters as in the simple substitution cipher and rather more complex Vigenère cipher systems then in use. The Playfair is thus significantly harder to break since the frequency analysis used for simple substitution ciphers does not work with it. The frequency analysis of bigrams is possible, but considerably more difficult. With 600 possible bigrams rather than the 26 possible monograms (single symbols, usually letters in this context), a considerably larger cipher text is required in order to be useful.