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N-Formylpiperidine

N-Formylpiperidine is an organic compound with the formula CHNO. It is the amide of formic acid and piperidine. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide (DMF). It has also been used to transfer the formyl group to a Grignard reagent:

PhCHCHMgCl + CHNO → PhCHCHCHO

In some formylation reaction of alkyllithium compounds, N-formylpiperidine gives higher yields than the DMF.