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J-coupling

Scalar or J-couplings (also called indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect interaction between two nuclear spins which arises from hyperfine interactions between the nuclei and local electrons. J-coupling contains information about bond distance and angles. Most importantly, J-coupling provides information on the connectivity of molecules. In NMR spectroscopy, it is responsible for the appearance of many signals in the NMR spectra of fairly simple molecules.