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The Collaborative International Dictionary
hit it off

hit it off \hit it off\ v. i. To get along well together; to be compatible; to work well together; -- of people in interactive situations; as, the new chemist hit it off immediately with his supervisor. [Colloq.]

Wiktionary
hit it off

vb. (context idiomatic English) To develop an amicable relationship (with), especially in a sudden manner during an initial encounter.

Usage examples of "hit it off".

He was about my grandfather's age, but we hit it off, and we were jabbering away when my mother walked in.

He met an attractive woman a few years his senior who was also biking coast-to-coast, and they hit it off.

Margaret disliked babies, but hit it off better with the two-year-old, and sent Dolly into fits of laughter by talking sense to him.

I gather they hit it off, but this is business, not personal, y'know?