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half-reaction

n. (context chemistry English) Either the oxidation or the reduction component of a redox reaction

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Half-reaction

A half reaction is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction.

Often, the concept of half-reactions is used to describe what occurs in an electrochemical cell, such as a Galvanic cell battery. Half-reactions can be written to describe both the metal undergoing oxidation (known as the anode) and the metal undergoing reduction (known as the cathode).

Half-reactions are often used as a method of balancing redox reactions. For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H ions to balance the hydrogen ions in the half reaction. For oxidation-reduction reactions in basic conditions, after balancing the atoms and oxidation numbers, first treat it as an acidic solution and then add OH ions to balance the H ions in the half reactions (which would give HO).