What is "fluorenylidene"

n. (context organic chemistry English) The divalent radical derived from the bridging methylene group of fluorene

9-Fluorenylidene is an aryl carbene derived from the bridging methylene group of fluorene. Fluorenylidene has the unusual property that the triplet ground state is only 1.1 kcal/mol (4.6 kJ/mol) lower in energy than the singlet state. For this reason, fluorenylidene has been studied extensively in organic chemistry.

Fluorenylidene is a reactive intermediate. Reactions involving fluorenylidene proceed through either the triplet or singlet state carbene, and the products formed depend on the relative concentration of spin states in solution, as influenced by experimental conditions. The rate of intersystem crossing is determined by the temperature and concentration of specific spin-trapping agents.