The Collaborative International Dictionary
Discalceate
Discalceate \Dis*cal"ce*ate\, v. t. [L. discalceatus unshod;
dis- + calceus shoe.]
To pull off shoes or sandals from. [Obs.]
--Cockeram.
Douglas Harper's Etymology Dictionary
discalceate
"unshod, barefoot," 1650s, from Latin discalceatus, from dis- (see dis-) + calceatus, past participle of calceare "to furnish with shoes," from calceus "shoe."
Wiktionary
discalceate
barefoot v
(context rare English) To remove shoes or other footwear.