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The Collaborative International Dictionary
Disaccustom

Disaccustom \Dis`ac*cus"tom\, v. t. [Cf. F. d['e]saccoutumer.] To destroy the force of habit in; to wean from a custom.
--Johnson.

Douglas Harper's Etymology Dictionary
disaccustom

late 15c., from Old French desacostumer "render unfamiliar" (Modern French désaccoutumer), from des- (see dis-) + acostumer (see accustom). Related: Disaccustomed.

Wiktionary
disaccustom

vb. to cause (someone) to break a habit or become unaccustomed to something that they are previously accustomed to

Usage examples of "disaccustom".

They see the peasant smiles very little, and altogether is not very kindly disposed and wants to disaccustom himself to the authorities.