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cantellation

n. (context geometry English) An operation in any dimension that cuts a regular polytope at its edges and vertex, creating a new facet in place of each edge and vertex.

Wikipedia
Cantellation (geometry)

In geometry, a cantellation is an operation in any dimension that bevels a regular polytope at its edges and vertices, creating a new facet in place of each edge and vertex. The operation also applies to regular tilings and honeycombs. This is also rectifying its rectification.

This operation (for polyhedra and tilings) is also called expansion by Alicia Boole Stott, as imagined by taking the faces of the regular form moving them away from the center and filling in new faces in the gaps for each opened vertex and edge.