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WordNet
call waiting

n. a way of letting you know that someone else is calling when you are using your telephone

Wikipedia
Call waiting

Call waiting is a telecommunication service offered by a telephony service provider to a subscriber by which the subscriber may suspend a telephone call already in progress to accept a second call. The subscriber may switch between calls, typically by using the hook flash signal.

Call waiting alleviates the need to have more than one telephone line for voice communications.