Wikipedia
Bismuth(III) oxide
Bismuth(III) oxide is perhaps the most industrially important compound of bismuth. It is also a common starting point for bismuth chemistry. It is found naturally as the mineral bismite (monoclinic) and sphaerobismoite (tetragonal, much more rare), but it is usually obtained as a by-product of the smelting of copper and lead ores. Bismuth trioxide is commonly used to produce the " Dragon's eggs" effect in fireworks, as a replacement of red lead.
Bismuth(III) oxide (data page)
This page provides supplementary chemical data on bismuth(III) oxide.