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Douglas Harper's Etymology Dictionary
at-

assimilated form of ad- "to, toward, before" before stems beginning in -t-; see ad-.

Wiktionary
at-

pre. (context obsolete no longer productive English) Prefix meaning at, close to, to, away, off.

Usage examples of "at-".

Her species' at-best benign neglect for their less accomplished fellow sapients was awful enough.