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photocatalysis

n. (context chemistry English) catalysis by a photocatalyst

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Photocatalysis

In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a catalyst. In catalysed photolysis, light is absorbed by an adsorbed substrate. In photogenerated catalysis, the photocatalytic activity (PCA) depends on the ability of the catalyst to create electron–hole pairs, which generate free radicals (e.g. hydroxyl radicals: •OH) able to undergo secondary reactions. Its practical application was made possible by the discovery of water electrolysis by means of titanium dioxide. The commercially used process is called the advanced oxidation process (AOP). There are several ways the AOP can be carried out; these may (but do not necessarily) involve TiO or even the use of UV light. Generally the defining factor is the production and use of the hydroxyl radical.

Usage examples of "photocatalysis".

Programs on supersonic reaction initiation, free radical mechanisms, photocatalysis, and selective adsorption would be quietly, even surreptitiously, phased out.

The thinness of the silica layer is critical: it has to be just thick enough to block the photocatalysis, but not so thick that it degrades the optical properties of the TiO2.